Tubes

The material filling the tube can be made of different materials, and it’s defined as “adsorbing phase” or “adsorbent” and interacts with the chemical compound blocking it on its surface through chemical reactions, creating both ionic or covalent intramolecular bondings, or physical interactions, such as with forming van der waals bondings.

IImportant characteristics of the sorbent tubes are the affinity, capability to interact with specific or groups of compounds, and the capability to release efficiently those compounds in particular conditions.
The reverse process is called “desorption” and the procedures which allow it to take place are the chemical or the themal desorption.
With the chemical desorption, an appropriate solvent is used to efficiently extract the sample from the support. For example. volatile organic compounds (VOCs) retained on charcoal tubes, are often desorbed using carbon sulfide.

The chemical desorption process require a skilled laboratory practice since the involved materials can be dangerous and expensive.
In the last years,the thermal desorption practice started to be used also for the sorbent tubes used for environmental or occupational hygiene samplings. This procedure, often automated, allow to extract the sample using high temperatures.